Chapter 19: Solubility and Complex-Ion Equilibria

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Chapter Objectives


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  1. Write the solubility product expression, Ksp, for a slightly soluble ionic compound.

  2. Calculate Ksp from the solubility of ionic compound or solubility from the value of Ksp.

  3. Calculate the effect of common ions on the aqueous solubilities of sparingly soluble salts.

  4. Determine if a salt will precipitate from solution based on the concentrations of its ions.

  5. Determine the concentration of ions remaining in solution after precipitation and predict whether precipitation will be complete.

  6. Explain how fractional precipitation works and when it can be used.

  7. Describe, through net ionic equations and calculations, the effect of pH on the precipitation and dissolving of certain substances.

  8. Write equations showing the effect of complex ion formation on other equilibrium processes such as solubility equilibria.

  9. Use complex ion formation constants, Kf (from table 19-2 or Appendix D in the text), to compute the concentrations in solution of: free ions, ligands, and complex ions.

  10. Use Kf values along with Ksp values to determine the solubilities of slightly soluble solutes in the presence of complexing ligands.

  11. Calculate the solubilities of certain solutes in the presence of complexing ligands.


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